Fabrication and Electrochemical Characterization of Polyaniline/Titanium Oxide Nanoweb Composite Electrode for Supercapacitor Application
- Title
- Fabrication and Electrochemical Characterization of Polyaniline/Titanium Oxide Nanoweb Composite Electrode for Supercapacitor Application
- Author
- 안희준
- Keywords
- Supercapacitor; Electrospinning; 3-D Template; Polyaniline; Titanium Oxide
- Issue Date
- 2016-03
- Publisher
- AMER SCIENTIFIC PUBLISHERS
- Citation
- JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v. 16, NO 3, Page. 2937-2943
- Abstract
- In this study, polyaniline/titanium oxide (PANi-TiO2) nanoweb composite was fabricated through electrochemical deposition and electrospinning techniques, and the composite was further utilized as an electrode for a supercapacitor. The PANi-TiO2 composite film showed three-dimensional hierarchical micro/nano architecture. The film was deposited on the current collector without the use of any binders. The morphology of the PANi-TiO2 composite film was confirmed by the use of field emission scanning electron microscopy (FE-SEM) analysis that polyaniline was grown in the form of nanorods with a diameter of 100 nm-200 nm on a TiO2 nanoweb. The chemical composition and quantitative analysis were determined by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). The electrochemical properties were analyzed by cyclic voltammetry (CV), chronopotentiometry, and electrochemical impedance spectroscopy (EIS). The result of electrochemical tests indicated that TiO2-PANi electrode displayed a high specific capacitance of 306.5 Fg(-1) at the scan rate of 20 mVs(-1), with the capacitance retention ratio being 103% after 500 cycles at the scan rate of 50 mVs(-1).
- URI
- http://www.ingentaconnect.com/content/asp/jnn/2016/00000016/00000003/art00131http://hdl.handle.net/20.500.11754/40613
- ISSN
- 1533-4880; 1533-4899
- DOI
- 10.1166/jnn.2016.11096
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > ORGANIC AND NANO ENGINEERING(유기나노공학과) > Articles
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