Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 주재범 | - |
dc.date.accessioned | 2018-02-23T07:26:05Z | - |
dc.date.available | 2018-02-23T07:26:05Z | - |
dc.date.issued | 2011-09 | - |
dc.identifier.citation | CHEMICAL PHYSICS LETTERS, Vol.514, No.4-6 [2011], p214-219 | en_US |
dc.identifier.issn | 0009-2614 | - |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0009261411010359 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11754/40466 | - |
dc.description.abstract | The ultraviolet absorption spectra of 2-fluoropyridine (2FPy) and 3-fluoropyridine (3FPy) vapors have been collected and assigned. For 2FPy about 150 bands were observed for the transitions to the vibronic levels of the S(p,p*) state at 38030.4cm-1. Both single quantum jump transitions to Aprime states and double quantum jumps transitions involving APrime modes were observed allowing most of the vibrational frequencies in the excited state to be identified. For 3FPy more than a hundred absorption bands associated with the S(n,p*) state at 35051.7cm-1 and about 40 broad bands associated with the S(p,p*) state at 37339cm-1 were observed. The experimental work was complemented by ab initio calculations. | en_US |
dc.description.sponsorship | This paper is dedicated to Terry A. Miller and his contributions to the field of molecular spectroscopy. The authors wish to thank the Robert A. Welch Foundation (Grant A-0396) for financial support. This research was also supported in part by the Intramural Research Program of the NIH, National Library of Medicine. Calculations were carried out on the Texas A&M Department of Chemistry Medusa computer system funded by the National Science Foundation, Grant No. CHE-0541587, and the Biowulf Linux cluster at the National Institutes of Health, Bethesda, MD (http://biowulf.nih.gov). | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier | en_US |
dc.subject | vibrational spectra | en_US |
dc.subject | ultraviolet absorption spectra | en_US |
dc.subject | electronic excited states | en_US |
dc.subject | molecular structure | en_US |
dc.subject | 2,6-difluoropyridine | en_US |
dc.title | Ultraviolet Absorption Spectra, Structure, Vibrations, and Theoretical Calculations of 2-Fluoro- and 3-Fluoropyridine in their Electronic Excited States | en_US |
dc.type | Article | en_US |
dc.relation.volume | 514 | - |
dc.identifier.doi | 10.1016/j.cplett.2011.08.054 | - |
dc.relation.page | 214-219 | - |
dc.relation.journal | CHEMICAL PHYSICS LETTERS | - |
dc.contributor.googleauthor | Boopalachandran, Praveenkumar | - |
dc.contributor.googleauthor | Kim, Sung-Hwan | - |
dc.contributor.googleauthor | Choo, Jae-Bum | - |
dc.contributor.googleauthor | Laane, Jaan | - |
dc.relation.code | 2011201810 | - |
dc.sector.campus | S | - |
dc.sector.daehak | GRADUATE SCHOOL[S] | - |
dc.sector.department | DEPARTMENT OF BIONANOTECHNOLOGY | - |
dc.identifier.pid | jbchoo | - |
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