Development of DA-type polymers with phthalimide derivatives as electron withdrawing units and a promising strategy for the enhancement of photovoltaic properties
- Title
- Development of DA-type polymers with phthalimide derivatives as electron withdrawing units and a promising strategy for the enhancement of photovoltaic properties
- Author
- 성태현
- Keywords
- Organic photovoltaics; Phthalimide; Conjugated polymers; Copolymerization
- Issue Date
- 2011-10
- Publisher
- ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
- Citation
- SOLAR ENERGY MATERIALS AND SOLAR CELLS , 95, 12, 3377-3384
- Abstract
- We report on two push-pull type polymer semiconductors involving phthalimide derivatives as electron withdrawing units. The solubility and energy level of phthalimide could be easily controlled by introducing various functional groups in its nitrogen site. Additionally, the V(oc) value of polymer semiconductor materials with phthalimide as an electron withdrawing unit could be efficiently enhanced because of the low HOMO energy level of phthalimide. Nevertheless, there are just a few of studies regarding the use of phthalimide in OPVs. In this study, we synthesized two photovoltaic polymer materials based on phthalimide with high V(oc) value, PFTPT and PCTPT. Between the two polymers. PCTPT/PC(71)BM-based photovoltaic cell afforded the best PCE value of 1.4% (V(oc)=0.94 V. J(sc)=4.41 mA/cm(2), FF=0.33) under 100 mW/cm(2) irradiation. In addition, a promising strategy for the development of high performance photovoltaic polymers with phthalimide derivatives as electron withdrawing units was investigated. (C) 2011 Elsevier B.V. All rights reserved.
- URI
- https://www.sciencedirect.com/science/article/pii/S092702481100451Xhttp://hdl.handle.net/20.500.11754/40095
- ISSN
- 0927-0248
- DOI
- 10.1016/j.solmat.2011.07.033
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > ELECTRICAL AND BIOMEDICAL ENGINEERING(전기·생체공학부) > Articles
- Files in This Item:
There are no files associated with this item.
- Export
- RIS (EndNote)
- XLS (Excel)
- XML