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Trifluoromethylation of heterocycles via visible light photoredox catalysis

Title
Trifluoromethylation of heterocycles via visible light photoredox catalysis
Author
조은진
Keywords
Visible light; Photoredox catalysis; Trifluoromethylation; Heterocycles; Ruthenium
Issue Date
2012-04
Publisher
PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Citation
TETRAHEDRON LETTERS, 53, 15, 2005-2008
Abstract
A method has been developed for the visible light-induced trifluoromethylation of heterocyclic compounds. A variety of electron-rich heterocycles were transformed into trifluoromethylated products by using CF3I as the trifluoromethyl radical source and Ru(bpy)3Cl2 as the photocatalyst under mild reaction conditions. This operationally simple and eco-friendly process can introduce trifluoromethyl groups without prefunctionalization.
URI
https://www.sciencedirect.com/science/article/pii/S0040403912002596http://hdl.handle.net/20.500.11754/38142
ISSN
0040-4039
DOI
10.1016/j.tetlet.2012.02.032
Appears in Collections:
GRADUATE SCHOOL[S](대학원) > BIONANOTECHNOLOGY(바이오나노학과) > Articles
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