Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 윤소원 | - |
dc.date.accessioned | 2018-02-14T05:26:41Z | - |
dc.date.available | 2018-02-14T05:26:41Z | - |
dc.date.issued | 2011-09 | - |
dc.identifier.citation | Journal of Organic Chemistry, Vol.76, No.17 [2011], p7204-7215 | en_US |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | https://pubs.acs.org/doi/abs/10.1021/jo201339z | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11754/37426 | - |
dc.description.abstract | Au(I)-catalyzed cyclization of alkenyl carbonyl compounds leading to a variety of substituted naphthalenes has been developed. This process exploits a dual function of the Au(I) catalyst: (1) the oxophilic nature of the Au(I) catalyst, counterintuitive to the pi-acidic reactivities generally associated with Au catalysts, and (2) olefin isomerization supported by the outcome of isotope scrambling experiments. It cannot be completely excluded that TfOH is a true operative catalyst in this protocol. In view of the practicality, the unnecessity of isomerically pure starting material in this reaction is particularly attractive and valuable. | en_US |
dc.description.sponsorship | This work was supported by the Mid-care Researcher Program (No.R01-2009-008-3940) and Basic Science Research Program (Nos.2010-0017149 and 2010-0007737) through the National Research Foundation of Korea (NRF) grant funded by the Ministry of Education, Science and Technology (MEST). A.R.J is grateful for 2009 NRF Postdoctoral Fellowship Program for Foreign Researchers (No.K20802001473-10B120004500). We gratefully acknowledge Professor Juyoung Yoon (Department of Chemistry and Nano Science, Ewha Womans University) for his generous support. | en_US |
dc.language.iso | en | en_US |
dc.publisher | AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA | en_US |
dc.subject | ACTIVATED METHYLENE-COMPOUNDS | en_US |
dc.subject | NAPHTHYL KETONE DERIVATIVES | en_US |
dc.subject | LEWIS-ACID | en_US |
dc.subject | SUBSTITUTED NAPHTHALENES | en_US |
dc.subject | REGIOSELECTIVE SYNTHESIS | en_US |
dc.subject | ORGANIC TRANSFORMATIONS | en_US |
dc.subject | INTRAMOLECULAR ADDITION | en_US |
dc.subject | CLAISEN REARRANGEMENT | en_US |
dc.subject | MEDIATED CYCLIZATION | en_US |
dc.subject | UNACTIVATED OLEFINS | en_US |
dc.title | Cyclization Reaction for the Synthesis of Polysubstituted Naphthalenes in the Presence of Au(I) Precatalysts | en_US |
dc.type | Article | en_US |
dc.relation.no | 17 | - |
dc.relation.volume | 76 | - |
dc.identifier.doi | 10.1021/jo201339z | - |
dc.relation.page | 7204-7215 | - |
dc.relation.journal | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.contributor.googleauthor | Jagdale, Arun R. | - |
dc.contributor.googleauthor | Park, Jong-Hyub | - |
dc.contributor.googleauthor | Youn, So-Won | - |
dc.relation.code | 2011205564 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF NATURAL SCIENCES[S] | - |
dc.sector.department | DEPARTMENT OF CHEMISTRY | - |
dc.identifier.pid | sowony73 | - |
dc.identifier.researcherID | 26647897000 | - |
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