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Acid-Catalyzed [3,3] Sigmatropic Rearrangement of N-Cbz-Diaryl Hydrazide for the Synthesis of Mono-N-Cbz-1,1 '-biaryl-2,2 '-diamine
- Title
- Acid-Catalyzed [3,3] Sigmatropic Rearrangement of N-Cbz-Diaryl Hydrazide for the Synthesis of Mono-N-Cbz-1,1 '-biaryl-2,2 '-diamine
- Author
- 조천규
- Keywords
- Sigmatropic rearrangement; Hydrazides; Cross-coupling; Biaryls; Amines; BAYLIS-HILLMAN ACETATES; BOC ARYL HYDRAZINES; ASYMMETRIC CATALYSIS; COUPLING REACTIONS; DIRECT OXIDATIONS; COMPLEXES; AZOBENZENES; DERIVATIVES; HALIDES; BINOL
- Issue Date
- 2011-01
- Publisher
- WILEY-V C H VERLAG GMBH, PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY
- Citation
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Vol.2011 No.3 [2011], 455-457
- Abstract
- N-Cbz-Diaryl hydrazides undergo acid-catalyzed [3,3] sigmatropic rearrangement to afford N-Cbz-1,1'-biaryl-2,2'-diamines. The resultant products can be versatile synthetic platforms for a wide variety of C-2- and/or nonsymmetric axially chiral ligands and organocatalysts.
- ISSN
- 1434-193X
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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