Au-I-Catalyzed Intramolecular Cyclization of 2-Alkenylphenyl Carbonyl Compounds: Exploring the Oxophilic Lewis Acidity of Au-I Species
- Title
- Au-I-Catalyzed Intramolecular Cyclization of 2-Alkenylphenyl Carbonyl Compounds: Exploring the Oxophilic Lewis Acidity of Au-I Species
- Author
- 윤소원
- Keywords
- Gold; Cyclization; Carbonyl compounds; Alkenes; Fused-ring systems
- Issue Date
- 2011-07
- Publisher
- WILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
- Citation
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY; JUL 2011, 20-21, p3904-p3910, 7p.
- Abstract
- A Au-I-catalyzed intramolecular cyclization reaction of 2-alkenylphenyl carbonyl compounds to afford a variety of indene, indenol, and indanone ring systems was developed. In this process, Au-I serves to activate the carbonyl group of beta-keto esters, aldehydes, and ketones, preferentially exhibiting oxophilicity in the presence of C-C multiple bonds. Furthermore, beta-keto esters could participate as the electrophilic partner in reactions with carbon nucleophile such as alkenes.
- URI
- http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201100113/abstracthttp://hdl.handle.net/20.500.11754/35839
- ISSN
- 1434-193X; 1099-0690
- DOI
- 10.1002/ejoc.201100113
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
- Files in This Item:
There are no files associated with this item.
- Export
- RIS (EndNote)
- XLS (Excel)
- XML