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Solvent-free solution processed passivation layer for improved long-term stability of organic field-effect transistors

Title
Solvent-free solution processed passivation layer for improved long-term stability of organic field-effect transistors
Author
장재영
Keywords
SOL-GEL PROCESS; HYBRID MATERIALS; THIN-FILMS; CONDENSATION; POLYMERS; DEVICES; WATER; AIR
Issue Date
2011-01
Publisher
ROYAL SOC CHEMISTRY
Citation
JOURNAL OF MATERIALS CHEMISTRY, v. 21, NO 3, Page. 775-780
Abstract
In an effort to realize organic field-effect transistors (OFETs) that are stable over long periods of time, we have designed an organic-inorganic hybrid passivation material (TGD622t) prepared via a nonhydrolytic sol-gel process that does not require the use of solvents. Fourier-transform infrared spectroscopy, atomic force microscopy, and UV-visible spectroscopy demonstrated the high density and low porosity of the organic-inorganic hybrid transparent TGD622t film after low-temperature curing (below 100 degrees C). The dense TGD622t passivation layer, which exhibited a water vapor transmission rate (WVTR) of 0.434 g m(-2) per day, effectively protected the poly[9,9-dioctylfluorenyl-2,7- diyl]-co-(bithiophene)]-based OFETs from humidity and oxygen in ambient air, resulting in a much more robust OFET performance with long-term stability relative to the operation of unpassivated devices.
URI
http://pubs.rsc.org/en/content/articlelanding/2011/jm/c0jm00898b
ISSN
0959-9428
DOI
10.1039/c0jm00898b
Appears in Collections:
COLLEGE OF ENGINEERING[S](공과대학) > ENERGY ENGINEERING(에너지공학과) > Articles
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