Cross-Coupling of Meyer-Schuster Intermediates under Dual Gold Photoredox Catalysis
- Title
- Cross-Coupling of Meyer-Schuster Intermediates under Dual Gold Photoredox Catalysis
- Author
- 신승훈
- Keywords
- DIARYLIODONIUM SALTS; CARBONYL-COMPOUNDS; RING EXPANSION; REARRANGEMENT; ALKENES; FUNCTIONALIZATION; ISOMERIZATION; COMPLEXES; ALCOHOLS; ALKYNES
- Issue Date
- 2016-02
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v. 18, NO 3, Page. 484-487
- Abstract
- Under dual gold/photoredox catalytic conditions, intermediates from the Meyer-Schuster rearrangement underwent an efficient cross-coupling with arene diazonium salts, leading to alpha-arylated enones. Diazonium salts assisted the dissociation of the propargyl hydroxyl group by forming alkoxydiazenes in the Meyer-Schuster rearrangement, and the coupling was proposed to proceed through an allenyl methyl ether.
- URI
- http://pubs.acs.org/doi/10.1021/acs.orglett.5b03531http://hdl.handle.net/20.500.11754/33973
- ISSN
- 1523-7060; 1523-7052
- DOI
- 10.1021/acs.orglett.5b03531
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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