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The cooperative FeCl3/DDQ system for the regioselective synthesis of 3-arylindoles from beta-monosubstituted 2-alkenylanilines

Title
The cooperative FeCl3/DDQ system for the regioselective synthesis of 3-arylindoles from beta-monosubstituted 2-alkenylanilines
Author
윤소원
Keywords
C-H AMINATION; 3-SUBSTITUTED INDOLES; ANNULATION; INHIBITORS; PHENOLS; ALKENES; HYDROAMINATION; ACTIVATION; CATALYSIS; ENAMINES
Issue Date
2016-02
Publisher
ROYAL SOC CHEMISTRY
Citation
ORGANIC & BIOMOLECULAR CHEMISTRY, v. 14, NO 7, Page. 2200-2204
Abstract
A highly regioselective synthesis of 3-arylindoles by using the cooperative FeCl3/DDQ system has been developed. This new protocol represents an attractive route for the synthesis of 3-arylindoles from readily accessible non-indole precursors, beta-arylsubstituted 2-styrylanilines, using an inexpensive catalyst and oxidant. Noteworthy is the unique synergetic and synergistic effect of FeCl3 and DDQ on the 1,2-aryl migratory process.
URI
http://pubs.rsc.org/en/Content/ArticleLanding/2016/OB/C6OB00074F#!divAbstracthttp://hdl.handle.net/20.500.11754/31885
ISSN
1477-0520; 1477-0539
DOI
10.1039/c6ob00074f
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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