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dc.contributor.author윤종승-
dc.date.accessioned2017-05-23T04:23:11Z-
dc.date.available2017-05-23T04:23:11Z-
dc.date.issued2015-09-
dc.identifier.citationJOURNAL OF ALLOYS AND COMPOUNDS, v. 644, Page. 464-469en_US
dc.identifier.issn0925-8388-
dc.identifier.issn1873-4669-
dc.identifier.urihttp://www.sciencedirect.com/science/article/pii/S0925838815013547-
dc.identifier.urihttp://hdl.handle.net/20.500.11754/27405-
dc.description.abstractThe Curie temperature of Mn5Ge3 was raised or lowered by alloying the compound with Fe or Co; hence, the temperature at which maximum magnetocaloric effect manifested was easily manipulated by forming Mn5-xGe3(Co,Fe)(x), alloys to ultimately develop a composite magnetic refrigerant consisting of multiple Mn5Ge3 - based alloys. The composite refrigerant was designed to produce a table-like Delta S-M-T curve and to maximize the RC value near room temperature. Linear combination of the Delta S-M-T curves for the constituent materials showed that a composite composed of physical mixture of four different Mn5Ge3-based compounds: Mn5Ge3, Mn5.1Ge2.9, Mn4.75Co0.25Ge3 and Mn4.75Fe0.25Ge3, generated an optimal Delta S-M-T curve with a table-like shape. The composite refrigerant with refrigeration capacity of 52 J kg(-1), peak entropy change at 300 K, and operating temperature range of 45 K under Delta H = 10 kOe was suitable for room-temperature magnetic refrigeration. Moreover, by changing the relative fraction of each constituent material in the composite, it was shown that the operating temperature range could be fine-tuned as needed. The calculated Delta S-M-T curve for the composite refrigerant by linear combination reasonably well matched the experimental Delta S-M-Tcurve estimated from the M-H curves of the composite refrigerant, suggesting that the simple linear combination of the experimental Delta S-M-T curves can be used to predict the performance of the composite magnetic refrigerants whose MCE was originated from the second order magnetic transition. In conclusion, being rare-earth free and lacking thermal or magnetic hysteresis, the Mn5Ge3 - based composite can be a competitive candidate magnetic refrigerant material operating at room temperature in terms of both economy and reliability compared to the giant MCE materials such as Gd - based intermetallic compounds or Heusler alloys. (C) 2015 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipThis work was supported by the Human Resource Development Program (No. 20114010203020) of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government Ministry of Trade, Industry and Energy.en_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE SAen_US
dc.subjectMagnetocaloric effecten_US
dc.subjectMagnetic refrigerationen_US
dc.subjectMn5Ge3en_US
dc.subjectComposite refrigeranten_US
dc.titleMagnetocaloric refrigerant with wide operating temperature range based on Mn5-xGe3(Co,Fe)(x) compositeen_US
dc.typeArticleen_US
dc.relation.volume644-
dc.identifier.doi10.1016/j.jallcom.2015.05.061-
dc.relation.page464-469-
dc.relation.journalJOURNAL OF ALLOYS AND COMPOUNDS-
dc.contributor.googleauthorKim, Yongdeok-
dc.contributor.googleauthorKang, Ki Hoon-
dc.contributor.googleauthorKim, Ju Hwan-
dc.contributor.googleauthorKim, Eun Jeong-
dc.contributor.googleauthorChoi, Kwangseok-
dc.contributor.googleauthorHan, Won Bae-
dc.contributor.googleauthorKim, Hee-Soo-
dc.contributor.googleauthorOh, Yoong-
dc.contributor.googleauthorYoon, Chong Seung-
dc.relation.code2015003408-
dc.sector.campusS-
dc.sector.daehakCOLLEGE OF ENGINEERING[S]-
dc.sector.departmentDIVISION OF MATERIALS SCIENCE AND ENGINEERING-
dc.identifier.pidcsyoon-
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COLLEGE OF ENGINEERING[S](공과대학) > MATERIALS SCIENCE AND ENGINEERING(신소재공학부) > Articles
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