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Indolocarbazole based small molecules: an efficient hole transporting material for perovskite solar cells

Title
Indolocarbazole based small molecules: an efficient hole transporting material for perovskite solar cells
Author
한성환
Keywords
ORGANOMETAL HALIDE PEROVSKITES; TITANIUM-DIOXIDE PHOTOANODES; PERFORMANCE; DEPOSITION; CONDUCTOR; IODIDE
Issue Date
2015-07
Publisher
ROYAL SOC CHEMISTRY
Citation
RSC ADVANCES, v. 5, NO 68, Page. 55321-55327
Abstract
To date, Spiro-OMeTAD, which is an expensive organic compound, has been used as the benchmark hole transporting material (HTM) in perovskite based solid state solar cells. Development of an inexpensive HTM with competitive performance to Spiro-OMeTAD is therefore significantly important for the commercialization of perovskite cells. Herein, an indolocarbazole based small molecule derivative (C12-carbazole) has been introduced as an environmentally stable, cost effective and highly efficient HTM. In contrast to the power conversion efficiency of 9.62% exhibited by the Spiro-OMeTAD based solid state solar cell, the C12-carbazole based device under the same experimental conditions has demonstrated an enhanced power conversion efficiency of 11.26%. The improved photovoltaic performance of the C12-carbazole based device is attributed to reduced carrier recombination by a better hole extraction ability of the C12-carbazole, which has demonstrated remarkably higher hole mobility compared to Spiro-OMeTAD.
URI
http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/C5RA10148D#!divAbstracthttp://hdl.handle.net/20.500.11754/26449
ISSN
2046-2069
DOI
10.1039/c5ra10148d
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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