Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이상욱 | - |
dc.date.accessioned | 2017-03-13T02:00:19Z | - |
dc.date.available | 2017-03-13T02:00:19Z | - |
dc.date.issued | 2015-07 | - |
dc.identifier.citation | ORGANOMETALLICS, v. 34, NO 14, Page. 3455-3458 | en_US |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.issn | 1520-6041 | - |
dc.identifier.uri | http://pubs.acs.org/doi/abs/10.1021/acs.organomet.5b00438 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11754/26048 | - |
dc.description.abstract | Heteroleptic tris-cyclometalated Ir(III) complexes supported by the o-carboranyl–phosphine ligand (CBP), (C∧N)2Ir(CBP) (C∧N = ppy (1), dfppy (2)), have been synthesized and characterized. The PL spectra of 1 and 2 displayed substantially blue shifted phosphorescence relative to the corresponding Ir(C∧N)3 complexes. Electrochemical and theoretical studies showed that the CBP ligand functioned as a strong-field ancillary ligand, and the greater HOMO stabilization in comparison to that of the LUMO by the CBP ligand was responsible for the increase in band gap, leading to a large blue shift in phosphorescence. | en_US |
dc.description.sponsorship | Financial support from the Basic Science Research Program (NRF-2014R1A1A2056364 for M.H.L.) and from the Priority Research Center Program (2009-0093818 for M.H.L.), through the National Research Foundation of Korea (NRF) is gratefully acknowledged. | en_US |
dc.language.iso | en | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.subject | LIGHT-EMITTING-DIODES | en_US |
dc.subject | IR(III) COMPLEXES | en_US |
dc.subject | STRATEGIC SYNTHESIS | en_US |
dc.subject | POLYHEDRAL BORANES | en_US |
dc.subject | RHODIUM COMPLEXES | en_US |
dc.subject | CRYSTAL-STRUCTURE | en_US |
dc.subject | ROOM-TEMPERATURE | en_US |
dc.subject | ENERGY-TRANSFER | en_US |
dc.subject | PHOTOPHYSICS | en_US |
dc.subject | EMISSION | en_US |
dc.title | o-Carboranyl–Phosphine as a New Class of Strong-Field Ancillary Ligand in Cyclometalated Iridium(III) Complexes: Toward Blue Phosphorescence | en_US |
dc.type | Article | en_US |
dc.relation.no | 14 | - |
dc.relation.volume | 34 | - |
dc.identifier.doi | 10.1021/acs.organomet.5b00438 | - |
dc.relation.page | 3455-3458 | - |
dc.relation.journal | ORGANOMETALLICS | - |
dc.contributor.googleauthor | Kim, Taewon | - |
dc.contributor.googleauthor | Lee, Junseong | - |
dc.contributor.googleauthor | Lee, Sang Uck | - |
dc.contributor.googleauthor | Lee, Min Hyung | - |
dc.relation.code | 2015000409 | - |
dc.sector.campus | S | - |
dc.sector.daehak | GRADUATE SCHOOL[S] | - |
dc.sector.department | DEPARTMENT OF BIONANOTECHNOLOGY | - |
dc.identifier.pid | sulee | - |
dc.identifier.researcherID | J-9027-2014 | - |
dc.identifier.orcid | http://orcid.org/0000-0001-9596-2349 | - |
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