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Catalytic allylic arylation of cinnamyl carbonates over palladium nanoparticles supported on a thermoresponsive polymer in water

Title
Catalytic allylic arylation of cinnamyl carbonates over palladium nanoparticles supported on a thermoresponsive polymer in water
Author
이학준
Keywords
MICHAEL/TSUJI-TROST REACTION; COUPLING REACTIONS; ACETATES; TETRAHYDROPYRANS; CONSTRUCTION; SUBSTITUTION; COMPLEXES; REGIO
Issue Date
2015-06
Publisher
ROYAL SOC CHEMISTRY
Citation
GREEN CHEMISTRY, v. 17, no. 6 , Page. 3579-3583
Abstract
Poly(NIPAM-co-4-VP) undergoes a phase transition at the low critical solution temperature with a change from the hydrophilic to the hydrophobic core in a hydrophilic solvent. Palladium nanoparticles supported on such a thermoresponsive polymer support were demonstrated to catalyze the Tsuji-Trost reaction for the arylation of various cinnamyl carbonates by arylboronic acids. Therefore, a protocol developed using mild reaction conditions demonstrates the recyclability of the catalyst in an eco-friendly solvent such as water.
URI
http://pubs.rsc.org/-/content/articlehtml/2015/gc/c5gc00745chttp://hdl.handle.net/20.500.11754/25770
ISSN
1463-9262; 1463-9270
DOI
10.1039/c5gc00745c
Appears in Collections:
GRADUATE SCHOOL[S](대학원) > BIONANOTECHNOLOGY(바이오나노학과) > Articles
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