Highly monodisperse magnetite/carbon composite microspheres with a mesoporous structure as high-performance lithium-ion battery anodes

Title
Highly monodisperse magnetite/carbon composite microspheres with a mesoporous structure as high-performance lithium-ion battery anodes
Authors
서경도
Keywords
FE3O4 NANOCRYSTALS; NEGATIVE-ELECTRODE; ALPHA-FE2O3; PARTICLES
Issue Date
2015-05
Publisher
ROYAL SOC CHEMISTRY
Citation
RSC ADVANCES, v. 5, Page. 42990-42996
Abstract
In this study, we propose a fabrication method for highly monodisperse magnetite/carbon (Fe3O4/C) composite microspheres with a mesoporous structure. Highly monodisperse porous polystyrene (PS) microspheres are synthesized by traditional seeded polymerization. Textural properties of porous PS microspheres can be controlled by using different amounts of diluent. In order to carbonize and introduce ferrous (Fe2+) and ferric (Fe3+) ions into the pores of PS microspheres, the sulfonation reaction is carried out using sulfuric acid. Fe3O4 nanocrystals are formed in the pores as well as on the surface of the sulfonated porous PS microspheres by a simple wet chemical method. The obtained mesoporous structure of the Fe3O4/C composite microspheres is still retained after a heat treatment in a nitrogen atmosphere. The homogeneous distribution of Fe3O4 nanocrystals in the porous carbon matrix was analyzed through elemental mapping by preparing cross-sections using focused ion beam scanning electron microscopy milling. When the composite electrodes are tested as an anode material in a Li-ion half-cell, the mesoporous Fe3O4/C composite microspheres exhibit not only a high reversible capacity of 562 mA h g(-1) after 100 cycles at 1 C but also good capacity retention at various current rates (0.1-10 C) with a high coulombic efficiency of above 99%.
URI
http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/C5RA05732A#!divAbstracthttp://hdl.handle.net/20.500.11754/24816
ISSN
2046-2069
DOI
http://dx.doi.org/10.1039/c5ra05732a
Appears in Collections:
COLLEGE OF ENGINEERING[S](공과대학) > CHEMICAL ENGINEERING(화학공학과) > Articles
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