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Selective Synthesis of Ruthenium(II) Metalla[2]Catenane via Solvent and Guest-Dependent Self-Assembly

Title
Selective Synthesis of Ruthenium(II) Metalla[2]Catenane via Solvent and Guest-Dependent Self-Assembly
Author
이상욱
Keywords
MOLECULAR BORROMEAN RINGS; COORDINATION CAGES; ORGANOMETALLIC CAGES; TEMPLATE SYNTHESIS; CHEMICAL TOPOLOGY; TREFOIL KNOT; SOLOMON LINK; CHEMISTRY; METALLARECTANGLES; CATENANE
Issue Date
2015-04
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v. 137, NO 14, Page. 4674-4677
Abstract
The coordination-driven self-assembly of an anthracene-functionalized ditopic pyridyl donor and a tetracene-based dinuclear Ru(II) acceptor resulted in an interlocked metalla[2]catenane, [M2L2](2), in methanol and a corresponding monorectangle, [M2L2], in nitromethane. Subsequently, guest template, solvent, and concentration effects allowed the self-assembly to be reversibly fine-tuned among monorectangle and catenane structures.
URI
http://pubs.acs.org/doi/abs/10.1021/jacs.5b02573http://hdl.handle.net/20.500.11754/23877
ISSN
0002-7863; 1520-5126
DOI
10.1021/jacs.5b02573
Appears in Collections:
GRADUATE SCHOOL[S](대학원) > BIONANOTECHNOLOGY(바이오나노학과) > Articles
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