Silver(I)-Mediated C-H Amination of 2-Alkenylanilines: Unique Solvent-Dependent Migratory Aptitude

Title
Silver(I)-Mediated C-H Amination of 2-Alkenylanilines: Unique Solvent-Dependent Migratory Aptitude
Authors
윤소원윤소원
Keywords
cyclization; indoles; migration; oxidation; silver
Issue Date
2015-01
Publisher
WILEY-V C H VERLAG GMBH
Citation
ADVANCED SYNTHESIS and CATALYSIS, v. 357, NO 1, Page. 227-234
Abstract
A highly effective silver(I)-mediated C-H amination of 2-alkenylanilines has been developed to afford a diverse range of substituted indoles. High functional group tolerance, broad substrate scope, simple/fast/high-yielding reaction, and recovery/reuse of the inexpensive silver oxidant are noteworthy. Furthermore, an uncommon migratory process of beta-monosubstituted 2-alkenylanilines with solvent-dependence was demonstrated.
URI
http://hdl.handle.net/20.500.11754/21592http://onlinelibrary.wiley.com/doi/10.1002/adsc.201400759/full
ISSN
1615-4169
DOI
http://dx.doi.org/10.1002/adsc.201400759
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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