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dc.contributor.author원호식-
dc.date.accessioned2023-08-09T01:27:28Z-
dc.date.available2023-08-09T01:27:28Z-
dc.date.issued2005-01-
dc.identifier.citationInternational Journal of Molecular Sciences, v. 6, NO. 1-2, Page. 87-96-
dc.identifier.issn1661-6596;1422-0067-
dc.identifier.urihttps://www.mdpi.com/1422-0067/6/1/87en_US
dc.identifier.urihttps://repository.hanyang.ac.kr/handle/20.500.11754/185248-
dc.description.abstractApplication of the extended Grunwald-Winstein equation to solvolyses of n-propyl chloroformate in a variety of pure and binary solvents indicates an addition-elimination pathway in the majority of the solvents but an ionization pathway in the solvents of highest ionizing power and lowest nucleophilicity. For methanolysis, a solvent deuterium isotope effect of 2.17 is compatible with the incorporation of general-base catalysis into the substitution process. Activation parameters are consistent with the duality of mechanism. Very modest positive salt effects are observed on adding chloride or bromide salts to the ethanolysis.-
dc.description.sponsorshipAcknowledgement is made to the donors of the American Chemical Society Petroleum Research Fund for partial support of this research.-
dc.languageen-
dc.publisherMultidisciplinary Digital Publishing Institute (MDPI)-
dc.subjectn-propyl chloroformate-
dc.subjectaddition-elimination-
dc.subjectionization-
dc.subjectsolvent isotope effect-
dc.subjectGrunwald-Winstein equation-
dc.titleApplication of the extended Grunwald-Winstein equation to solvolyses of n-propyl chloroformate-
dc.typeArticle-
dc.relation.no1-2-
dc.relation.volume6-
dc.identifier.doi10.3390/i6010087-
dc.relation.page87-96-
dc.relation.journalInternational Journal of Molecular Sciences-
dc.contributor.googleauthorKyong, Jin Burm-
dc.contributor.googleauthorWon, Hoshik-
dc.contributor.googleauthorKevill, Dennis N.-
dc.sector.campusE-
dc.sector.daehak과학기술융합대학-
dc.sector.department화학분자공학과-
dc.identifier.pidhswon-


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