Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이용우 | - |
dc.date.accessioned | 2023-07-24T01:14:48Z | - |
dc.date.available | 2023-07-24T01:14:48Z | - |
dc.date.issued | 2009-10 | - |
dc.identifier.citation | Bulletin of the Korean Chemical Society, v. 30, NO. 10, Page. 2408-2412 | - |
dc.identifier.issn | 0253-2964;1229-5949 | - |
dc.identifier.uri | https://www.kci.go.kr/kciportal/ci/sereArticleSearch/ciSereArtiView.kci?sereArticleSearchBean.artiId=ART001526341 | en_US |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/184194 | - |
dc.description.abstract | The specific rates of solvolysis of methyl fluoroformate have been measured at 40 0 degrees C in several hydroxylic solvents. Analysis with the extended Grunwald-Winstein equation leads to sensitivities toward changes in solvent nucleophilicity (l) of 1 33 +/- 0.10 and toward changes in solvent ionizing power (m) 0.73 +/- 0 06. For methanolysis, a solvent deuterium isotope effect of 3.98 is compatible with the incorporation of general-base catalysis into the Substitution process. For four representative solvents, studies were made at several temperatures and activation parameters determined. These observations are also compared with those previously reported for alkyl halogen-formate esters and mechanistic conclusions are drawn. | - |
dc.language | en | - |
dc.publisher | 대한화학회 | - |
dc.subject | Methyl fluoroformate | - |
dc.subject | Addition-elimination | - |
dc.subject | Grunwald-Winstein equation | - |
dc.subject | Solvent isotope effect | - |
dc.title | Correlation of the Rates of Solvolysis of Methyl Fluoroformate Using the Extended Grunwald-Winstein Equation | - |
dc.type | Article | - |
dc.relation.no | 10 | - |
dc.relation.volume | 30 | - |
dc.identifier.doi | 10.5012/bkcs.2009.30.10.2408 | - |
dc.relation.page | 2408-2412 | - |
dc.relation.journal | Bulletin of the Korean Chemical Society | - |
dc.contributor.googleauthor | Seong, Mi Hye | - |
dc.contributor.googleauthor | Choi, Song Hee | - |
dc.contributor.googleauthor | Lee, Yong-Woo | - |
dc.contributor.googleauthor | Kyong, Jin Burm | - |
dc.contributor.googleauthor | Kim, Dong Kook | - |
dc.contributor.googleauthor | Kevill, Dennis N. | - |
dc.sector.campus | E | - |
dc.sector.daehak | 과학기술융합대학 | - |
dc.sector.department | 화학분자공학과 | - |
dc.identifier.pid | yongwoolee | - |
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