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Efficient Palladium-Catalyzed Coupling of Baylis-Hillman Acetates with an Allylstannane

Title
Efficient Palladium-Catalyzed Coupling of Baylis-Hillman Acetates with an Allylstannane
Author
이학준
Keywords
Baylis-Hillman acetates; allyltributylstannane; bis-pi-allylpalladium; 1,5-diene; allylation
Issue Date
2010-02
Publisher
Georg Thieme Verlag
Citation
Synthesis, NO. 4, Page. 661-665
Abstract
Acetates of Baylis-Hillman adducts derived from ethyl acrylate, methyl vinyl ketone, and acrylonitrile were coupled with allyltributylstannane using Pd(PPh3)(4) or Pd(dba)(2) as the catalyst at room temperature to afford the corresponding trisubstituted alka-1,5-dienes in good to high yields.
URI
https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0029-1218612https://repository.hanyang.ac.kr/handle/20.500.11754/183985
ISSN
0039-7881;1437-210X
DOI
10.1055/s-0029-1218612
Appears in Collections:
COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > CHEMICAL AND MOLECULAR ENGINEERING(화학분자공학과) > Articles
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