Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이상욱 | - |
dc.date.accessioned | 2022-11-28T01:01:01Z | - |
dc.date.available | 2022-11-28T01:01:01Z | - |
dc.date.issued | 2015-07 | - |
dc.identifier.citation | Organometallics, v. 34.0, NO. 14, Page. 3455-3458 | - |
dc.identifier.issn | 0276-7333;1520-6041 | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.organomet.5b00438 | en_US |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/177532 | - |
dc.description.abstract | Heteroleptic tris-cyclometalated Ir(III) complexes supported by the o-carboranyl-phosphine ligand (CBP), (C boolean AND N)(2)Ir(CBP) (C boolean AND N = ppy (1), dfppy (2)), have been synthesized and characterized. The PL spectra of 1 and 2 displayed substantially blue shifted phosphorescence relative to the corresponding Ir(C boolean AND N)(3) complexes. Electrochemical and theoretical studies showed that the CBP ligand functioned as a strong-field ancillary ligand, and the greater HOMO stabilization in comparison to that of the LUMO by the CBP ligand was responsible for the increase in band gap, leading to a large blue shift in phosphorescence. | - |
dc.description.sponsorship | Financial support from the Basic Science Research Program (NRF-2014R1A1A2056364 for M.H.L.) and from the Priority Research Center Program (2009-0093818 for M.H.L.), through the National Research Foundation of Korea (NRF) is gratefully acknowledged. | - |
dc.language | en | - |
dc.publisher | American Chemical Society | - |
dc.title | o-Carboranyl Phosphine as a New Class of Strong-Field Ancillary Ligand in Cyclometalated Iridium(III) Complexes: Toward Blue Phosphorescence | - |
dc.type | Article | - |
dc.relation.no | 14 | - |
dc.relation.volume | 34.0 | - |
dc.identifier.doi | 10.1021/acs.organomet.5b00438 | - |
dc.relation.page | 3455-3458 | - |
dc.relation.journal | Organometallics | - |
dc.contributor.googleauthor | Kim, Taewon | - |
dc.contributor.googleauthor | Lee, Junseong | - |
dc.contributor.googleauthor | Lee, Sang Uck | - |
dc.contributor.googleauthor | Lee, Min Hyung | - |
dc.sector.campus | E | - |
dc.sector.daehak | 과학기술융합대학 | - |
dc.sector.department | 화학분자공학과 | - |
dc.identifier.pid | sulee | - |
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