Intact Crystalline Semiconducting Graphene Nanoribbons from Unzipping Nitrogen-Doped Carbon Nanotubes
- Title
- Intact Crystalline Semiconducting Graphene Nanoribbons from Unzipping Nitrogen-Doped Carbon Nanotubes
- Author
- 정문석
- Keywords
- unzipping; graphene; nanoribbon; gas sensor; doping
- Issue Date
- 2019-09
- Publisher
- AMER CHEMICAL SOC
- Citation
- ACS APPLIED MATERIALS & INTERFACES, v. 11, no. 41, page. 38006-38015
- Abstract
- Unzipping carbon nanotubes (CNTs) may offer a valuable route to synthesize graphene nanoribbon (GNR) structures with semiconducting properties. Unfortunately, currently available unzipping methods commonly rely on a random harsh chemical reaction and thereby cause significant degradation of the crystalline structure and electrical properties of GNRs. Herein, crystalline semiconducting GNRs are achieved by a synergistic, judiciously designed two-step unzipping method for N-doped CNTs (NCNTs). NCNTs are effectively unzipped by damage-minimized, dopant-specific electrochemical unzipping and subsequent sonochemical treatment into long ribbon-like nanostructures with crystalline basal planes. Owing to the nanoscale dimension originating from the dense nucleation of the unzipping reaction at highly NCNTs, the resultant GNRs demonstrate semiconducting properties, which can be exploited for chemiresistor-type gas-sensing devices and many other applications.
- URI
- https://pubs.acs.org/doi/10.1021/acsami.9b08876https://repository.hanyang.ac.kr/handle/20.500.11754/160771
- ISSN
- 1944-8244; 1944-8252
- DOI
- 10.1021/acsami.9b08876
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > PHYSICS(물리학과) > Articles
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