Random Copolymerization of Polythiophene for Simultaneous Enhancement of In-plane and Out-of-plane Charge Transport for Organic Transistors and Perovskite Solar Cells
- Title
- Random Copolymerization of Polythiophene for Simultaneous Enhancement of In-plane and Out-of-plane Charge Transport for Organic Transistors and Perovskite Solar Cells
- Author
- 고성연
- Alternative Author(s)
- 고성연
- Advisor(s)
- 고민재
- Issue Date
- 2021. 2
- Publisher
- 한양대학교
- Degree
- Master
- Abstract
- High-performance conjugated polymers for electronic applications can be developed by modulating an appropriate chemical structure that optimizes their crystal characteristics and charge transport behavior. Herein, we demonstrated the simultaneous enhancement of the in-plane and out-of-plane charge transport of polythiophenes by random polymerization. We synthesized a polythiophene polymer by varying the ratio of two different dialkyl-substituted bi-thiophene and triethylene glycol substituted mono-thiophene units; this polymer exhibited weakened orientation preferences of polymer crystallite films, a denser packing, and a more homogeneous surface morphology in comparison with its homopolymer analogue. Furthermore, this optimized random polymer afforded an enhanced in-plane mobility of 7.72 cm2 V–1 s–1, measure by field-effect transistor, and out-of-plane mobility of 8.86 × 10–4 cm2 V–1 s–1, measure by space-charge-limited-current device. These are respectively 2.4 times and 10 times higher than the mobilities of the homopolymer (field-effect mobility = 3.25 cm2 V–1 s–1 and space-charge-limited-current mobility = 8.73 × 10–5 cm2 V–1 s–1). The enhanced charge transport in out-of-plane direction was also confirmed by fabricating perovskite solar cells using optimized polythiophene as a hole-transporting material, which exhibited a higher efficiency of nearly 16.2% than the device with homopolymer analogue (12.0%).
- URI
- https://repository.hanyang.ac.kr/handle/20.500.11754/158990http://hanyang.dcollection.net/common/orgView/200000485688
- Appears in Collections:
- GRADUATE SCHOOL[S](대학원) > CHEMICAL ENGINEERING(화학공학과) > Theses (Master)
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