Fabrication of conductive and printable nano carbon ink for wearable electronic and heating fabrics

Abstract

Printable Nano carbon colloidal ink has fascinated great attention due to their exceptional potential for large-scale application for powering wearable electronic devices. Though, it is challenging to incorporate various characteristics together such as mechanical stability, solution printability, conductivity, electrocatalytic activity, and heat generating properties in the flexible fabric based electrode system. In this research the development of printable composites made with woven/nonwoven fabrics printed with multiwall carbon nanotubes for flexible and wearable heating system and cathodes for dye-sensitized solar cells (DSSC), respectively. We report a printable carbon ink of multiwall carbon nanotubes (MWCNT) synthesized by globular protein serum bovine albumin (BSA). BSA is amino-rich dispersant used to disperse MWCNT and generate tubular porous carbon matrix. High loading ratio of BSA increases the dispersing power of MWCNT and increased porosity of CNT matrix. The proposed Organic Nanocarbon ink (Organic NC) serve the pathways for electron transport leading to higher heat dissipation as the well high conductivity and electrocatalytic activity. It was interesting to reveal that different kinds of woven and nonwoven fabrics displayed exceptional thermal properties when DC voltage was applied. The heat generating properties were highly dependent on the type of fabric and conductive ink uptake. Our proposed Organic NC printed fabric system exhibited superior conductivity with 15-20 Omega resistivity and lower charge transfer resistance R-C(T) = 2.69 Omega, demonstrated an 8% power conversion efficiency of DSSC. The proposed research paves the ways for solution printable high performance woven and nonwoven conductive and thermoelectric materials for wearable electronics. (C) 2018 Elsevier Inc. All rights reserved.