Dual sensitization of MWCNTs by co-decoration with p- and n-type metal oxide nanoparticles

Abstract

We present a dual sensitization gas sensor for selective detection of either H2S or C2H5OH gases, based on ZnO/CuO nanoparticle (NP)-decorated MWCNTs. First, Cu-Zn layers of three different thickness (3, 6, 9 nm) were successfully deposited on the surfaces of CNTs by a sputtering process and subsequently converted to their corresponding oxides by thermal annealing. The gas sensing characteristics of metal oxide decorated-MWCNTs were studied in the presence of three gases, namely NO2, H2S, and C2H5OH. The best sensing properties were obtained when the Cu-Zn deposition layer was 6 nm thick. The optimized sensor showed extraordinary responses to both H2S and C2H5OH gases at working temperatures of 100 degrees C and 200 degrees C, respectively. Therefore, selectivity was tuned by selection of the working temperature. The sensing mechanisms of the metal oxide-decorated CNTs sensors are discussed in detail. The approach described, namely co-decoration of the surfaces of MWCNTs with different metal oxides, will be of great utility to researchers who wish to fabricate dual sensitive gas sensors. (C) 2018 Elsevier B.V. All rights reserved.