Thermoresponsive Amphoteric Metal–Organic Frameworks for Efficient and Reversible Adsorption of Multiple Salts from Water
- Title
- Thermoresponsive Amphoteric Metal–Organic Frameworks for Efficient and Reversible Adsorption of Multiple Salts from Water
- Author
- 김승주
- Keywords
- amphoteric; desalination; metal-organic frameworks; regenerable salt adsorbents; thermoresponsive
- Issue Date
- 2018-07
- Publisher
- WILEY-V C H VERLAG GMBH
- Citation
- ADVANCED MATERIALS, v. 30, no. 34, Article no. 1802767
- Abstract
- Regenerable, high-efficiency salt sorption materials are highly desirable for water treatment. Here, a thermoresponsive, amphoteric metal-organic framework (MOF) material is reported that can adsorb multiple salts from saline water at room temperature and effectively release the adsorbed salts into water at elevated temperature (e.g., 80 degrees C). The amphoteric MOF, integrated with both cation-binding carboxylic groups and anion-binding tertiary amine groups, is synthesized by introducing a polymer with tertiary amine groups into the cavities of a water-stable MOF such as MIL-121 with carboxylic groups inside its frameworks. The amphoterized MIL-121 exhibits excellent salt adsorption properties, showing stable adsorption-desorption cycling performances and high LiCl, NaCl, MgCl2, and CaCl2 adsorption capacities of 0.56, 0.92, 0.25, and 0.39 mmol g(-1), respectively. This work provides a novel, effective strategy for synthesizing new-generation, environmental-friendly, and responsive salt adsorption materials for efficient water desalination and purification.
- URI
- https://onlinelibrary.wiley.com/doi/abs/10.1002/adma.201802767https://repository.hanyang.ac.kr/handle/20.500.11754/119392
- ISSN
- 0935-9648; 1521-4095
- DOI
- 10.1002/adma.201802767
- Appears in Collections:
- CENTER FOR CREATIVE CONVERGENCE EDUCATION[S](창의융합교육원) > ETC
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