Effect of alkali and alkaline earth metal on Co/CeO2 catalyst for the water gas shift reaction of waste derived synthesis gas
- Title
- Effect of alkali and alkaline earth metal on Co/CeO2 catalyst for the water gas shift reaction of waste derived synthesis gas
- Author
- 전병훈
- Keywords
- Waste derived synthesis gas; High temperature water-gas shift; Alkaline earth metal; Co/CeO2; Stability; Sintering resistance
- Issue Date
- 2018-02
- Publisher
- ELSEVIER SCIENCE BV
- Citation
- APPLIED CATALYSIS A-GENERAL, v. 551, page. 63-70
- Abstract
- We prepared a series of alkali (Na and K) and alkaline earth metal (Ca and Ba) promoted Co/CeO2 catalysts to investigate the effect of the promoter on the catalytic performance of the catalyst in the high-temperature water gas shift (WGS) reaction of waste derived synthesis gas. Interestingly, alkali metal promoted catalysts deactivated rapidly compared to alkaline earth metal promoted catalysts. Alkaline earth metal promoted catalysts showed relatively higher stability (>50 h) even at a very high gas hourly space velocity of 143,000 h(-1). X-ray diffraction (XRD) and transmission electron microscopy (TEM) results reveal that the higher stability of the alkaline earth metal promoted catalysts was due to the strong resistance to sintering, showing a relatively small crystallite size of metallic cobalt compared to the alkali metal promoted catalysts after WGS reaction.
- URI
- https://www.sciencedirect.com/science/article/abs/pii/S0926860X1730563X?via%3Dihubhttps://repository.hanyang.ac.kr/handle/20.500.11754/117669
- ISSN
- 0926-860X; 1873-3875
- DOI
- 10.1016/j.apcata.2017.12.009
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > EARTH RESOURCES AND ENVIRONMENTAL ENGINEERING(자원환경공학과) > Articles
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