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Electrochemical Performance of M2GeO4 (M = Co, Fe and Ni) as Anode Materials with High Capacity for Lithium-Ion Batteries

Title
Electrochemical Performance of M2GeO4 (M = Co, Fe and Ni) as Anode Materials with High Capacity for Lithium-Ion Batteries
Author
김동원
Keywords
M2GeO4 electrode; Anode material; Lithium-ion battery; Carbon coating
Issue Date
2017-12
Publisher
KOREAN ELECTROCHEMISTRY SOC
Citation
JOURNAL OF ELECTROCHEMICAL SCIENCE AND TECHNOLOGY, v. 8, no. 4, page. 323-330
Abstract
M2GeO4 (M = Co, Fe and Ni) was synthesized as an anode material for lithium-ion batteries and its electrochemical characteristics were investigated. The Fe2GeO4 electrode exhibited an initial discharge capacity of 1127.8 mAh g(-1) and better capacity retention than Co2GeO4 and Ni2GeO4. A diffusion coefficient of lithium ion in the Fe2GeO4 electrode was measured to be 12.7 x 10(-8) cm(2) s(-1), which was higher than those of the other two electrodes. The electrochemical performance of the Fe2GeO4 electrode was improved by coating carbon onto the surface of Fe2GeO4 particles. The carbon-coated Fe2GeO4 electrode delivered a high initial discharge capacity of 1144.9 mAh g(-1) with good capacity retention. The enhanced cycling performance was mainly attributed to the carbon-coated layer that accommodates the volume change of the active materials and improves the electronic conductivity. Our results demonstrate that the carbon-coated Fe2GeO4 can be a promising anode material for achieving high energy density lithium-ion batteries.
URI
https://www.jecst.org/journal/view.php?doi=10.33961/JECST.2017.8.4.323http://repository.hanyang.ac.kr/handle/20.500.11754/116526
ISSN
2093-8551
DOI
10.5229/JECST.2017.8.4.323
Appears in Collections:
COLLEGE OF ENGINEERING[S](공과대학) > CHEMICAL ENGINEERING(화학공학과) > Articles
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