Facile Nanostructured Composite Synthesis of Selenium and Molybdenum Chalcogenides/Carbon Nanotubes for Li-Ion Batteries
- Title
- Facile Nanostructured Composite Synthesis of Selenium and Molybdenum Chalcogenides/Carbon Nanotubes for Li-Ion Batteries
- Author
- 이성철
- Keywords
- Rechargeable lithium-ion batteries; Hydrothermal method; Se-doped MoS2; Carbon nanotube; Hybrid structure
- Issue Date
- 2017-10
- Publisher
- WILEY-V C H VERLAG GMBH
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v. 38, no. 11, page. 1347-1352
- Abstract
- For lithium-ion batteries (LIBs), MoS2, which has conversion reaction pathways that can accommodate lithium ions during charge, is a very special inorganic material that has a two-dimensional planar structure similar to graphite. For reliable performance of high-energy LIBs, Se-molybdenum chalcogenides with sulfide and selenide (Se-MC) were prepared via the incorporation of a carbon nanotube (CNT) conducting matrix to solve the crucial limitations of MoS2, which include poor electronic conductivity and severe volume changes during cycling. For the preparation of Se-MC/CNT, a facile, one-pot synthetic method using molybdic acid, selenium dioxide, and thioacetamide, which are the precursors for molybdenum, selenide, and sulfide, respectively, and CNT was developed. A detailed investigation of the surfaces and crystal structures of the prepared samples was conducted using transmission electron microscopy and X-ray photoelectron spectroscopy analyses. Furthermore, LIBs containing the Se-MC/CNT exhibited a significantly extended cycle life and an improved rate capability that revealed the synergetic effect of the CNTs and selenide for controlling the morphology.
- URI
- https://onlinelibrary.wiley.com/doi/abs/10.1002/bkcs.11300https://repository.hanyang.ac.kr/handle/20.500.11754/115819
- ISSN
- 1229-5949
- DOI
- 10.1002/bkcs.11300
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > CHEMICAL ENGINEERING(화학공학과) > Articles
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