Effect of aging temperature during refluxing on the textural and surface acidic properties of zirconia catalysts
- Title
- Effect of aging temperature during refluxing on the textural and surface acidic properties of zirconia catalysts
- Author
- 서영웅
- Keywords
- Zirconia; Reflux; Aging temperature; Acid properties; Dehydration
- Issue Date
- 2017-10
- Publisher
- ELSEVIER SCIENCE INC
- Citation
- JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v. 54, page. 137-145
- Abstract
- Hydrous zirconia was synthesized via precipitation method, and effect of aging temperature during refluxing (30-100 degrees C) precursor solution was investigated. We found that the aging temperature influenced on structural and textural properties of the hydrous zirconia, with variations in the textural properties leading to changes in the surface properties of calcined zirconia, including the acid functionalities. In addition, ZrO2 aged at 100 degrees C exhibited the highest specific surface area and the highest Lewis and Bronsted acidities among the samples. Finally, enhanced catalytic activity was also observed for the ZrO2 samples prepared at higher aging temperatures in the dehydration of iso-propanol. (C) 2017 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
- URI
- https://www.sciencedirect.com/science/article/pii/S1226086X17302630?via%3Dihubhttps://repository.hanyang.ac.kr/handle/20.500.11754/115810
- ISSN
- 1226-086X; 1876-794X
- DOI
- 10.1016/j.jiec.2017.05.026
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > CHEMICAL ENGINEERING(화학공학과) > Articles
- Files in This Item:
There are no files associated with this item.
- Export
- RIS (EndNote)
- XLS (Excel)
- XML