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A Kinetic Study of the Solvolyses of Methyl and Ethyl Chloroglyoxalates
- Title
- A Kinetic Study of the Solvolyses of Methyl and Ethyl Chloroglyoxalates
- Author
- 경진범
- Issue Date
- 2005-05
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF ORGANIC CHEMISTRY, v. 70, No. 22, Page. 9032-9035
- Abstract
- Solvolyses of methyl and ethyl chloroglyoxalates proceed about 106 time faster than the idential solvolyses of the corresponding chloroformates. The correlation parameters obtained from application of the extended Grunwald-Winstein equation are consistent with an addition-elimination mechenism over the full range of solvent, with the addition step being rate determining.
- URI
- https://pubs.acs.org/doi/10.1021/jo050998mhttps://repository.hanyang.ac.kr/handle/20.500.11754/110560
- ISSN
- 0022-3263
- Appears in Collections:
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > CHEMICAL AND MOLECULAR ENGINEERING(화학분자공학과) > Articles
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