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A Kinetic Study of the Solvolyses of Methyl and Ethyl Chloroglyoxalates

Title
A Kinetic Study of the Solvolyses of Methyl and Ethyl Chloroglyoxalates
Author
경진범
Issue Date
2005-05
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF ORGANIC CHEMISTRY, v. 70, No. 22, Page. 9032-9035
Abstract
Solvolyses of methyl and ethyl chloroglyoxalates proceed about 106 time faster than the idential solvolyses of the corresponding chloroformates. The correlation parameters obtained from application of the extended Grunwald-Winstein equation are consistent with an addition-elimination mechenism over the full range of solvent, with the addition step being rate determining.
URI
https://pubs.acs.org/doi/10.1021/jo050998mhttp://repository.hanyang.ac.kr/handle/20.500.11754/110560
ISSN
0022-3263
DOI
10.1021/jo050998m
Appears in Collections:
COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > CHEMICAL AND MOLECULAR ENGINEERING(화학분자공학과) > Articles
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