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dc.contributor.author나명수-
dc.date.accessioned2019-09-04T05:46:18Z-
dc.date.available2019-09-04T05:46:18Z-
dc.date.issued2005-02-
dc.identifier.citationINORGANIC CHEMISTRY, v. 44, No. 6, Page. 1934-1940en_US
dc.identifier.issn0020-1669-
dc.identifier.issn1520-510X-
dc.identifier.urihttps://pubs.acs.org/doi/10.1021/ic0486872-
dc.identifier.urihttp://repository.hanyang.ac.kr/handle/20.500.11754/110195-
dc.description.abstractBy modulating the secondary building units derived from the primary building units, N-acylsalicylhydrazides (H-3-xshz), we have been able to construct isostructural but tunable host networks, [Mn-6(xshZ)(6)(dmf)(2)(bpea)(2)], with different cavity sizes and shapes where the secondary building units, [Mn-6(xshz)(6)], were linked through exo-bidentate bridging ligand, 1,2-bis(pyridyl)ethane (bpea) to form 3-D networks. With a short length linear N-acyl side chain at the primary building unit, the host networks have a 3-D network with three-dimensional cavities. With an appropriate length linear N-acyl side chain at the primary building unit, the host network keeps the isostructural 3-D network but with two types of one-dimensional channels of reduced cavity volume. The tuned host networks showed not only size selectivity for the guest molecules but also shape selectivity. While the three-dimensional channeled host showed selectivity depending on the length of the podal guests, the one-dimensional channeled host showed selectivity depending on both the length and/or the podality of the guest molecules.en_US
dc.description.sponsorshipWe thank the Korean Institute of Basic Science for elemental analyses. The authors wish to acknowledge the financial support of KISTEP (M1-0213-03-0004) and CBMH.en_US
dc.language.isoen_USen_US
dc.publisherAMER CHEMICAL SOCen_US
dc.titleSize and Shape Selectivity of Host Networks Built Based on Tunable Secondary Building Unitsen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/ic0486872-
dc.relation.journalINORGANIC CHEMISTRY-
dc.contributor.googleauthorMoon, D-
dc.contributor.googleauthorLah, MS-
dc.relation.code2009204045-
dc.sector.campusE-
dc.sector.daehakCOLLEGE OF SCIENCE & TECHNOLOGY[E]-
dc.sector.departmentDIVISION OF SCIENCE & TECHNOLOGY-
dc.identifier.pidmslah-
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COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > ETC
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