Metalladiazamacrocycles: Metallamacrocycles as Potential Supramolecular Host System for Small Organic Guest Molecules and Supramolecular Building Blocks for Metal Organic Frameworks
- Title
- Metalladiazamacrocycles: Metallamacrocycles as Potential Supramolecular Host System for Small Organic Guest Molecules and Supramolecular Building Blocks for Metal Organic Frameworks
- Author
- 나명수
- Keywords
- metalladiazamacrocycle; metallamacrocycle; supramolecular host system; supramolecular building block; metal-organic framework
- Issue Date
- 2007-08
- Publisher
- TAYLOR & FRANCIS LTD
- Citation
- SUPRAMOLECULAR CHEMISTRY, v. 19, No. 4-5, Page. 295-308
- Abstract
- Metalladiazamacrocycles, coordination driven potential supramolecular host systems, can be obtained via cyclic linkages of the metal ions and the bridging ligands, N-acylsalicylhydrazides. The nuclearity and the shape of the metallamacrocycles could be modulated by controlling the steric interactions caused by N-acyl tails of the ligands. The macrocycles could be utilized for recognition of small organic guest molecules using their hydrophobicity/hydrophilicity, the size and shape/symmetry of the cavities. In addition, these macrocycles can be used as the supramolecular building blocks for the construction of systematically tuned metal-organic frameworks since these clusters have several replaceable solvent sites which could serve as connecting nodes for the formaton of network structures.
- URI
- https://www.tandfonline.com/doi/full/10.1080/10610270701275083https://repository.hanyang.ac.kr/handle/20.500.11754/106833
- ISSN
- 1061-0278; 1029-0478
- DOI
- 10.1080/10610270701275083
- Appears in Collections:
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > ETC
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