Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 유원철 | - |
dc.date.accessioned | 2019-05-22T01:24:02Z | - |
dc.date.available | 2019-05-22T01:24:02Z | - |
dc.date.issued | 2018-02 | - |
dc.identifier.citation | ACS SUSTAINABLE CHEMISTRY & ENGINEERING, v. 6, No. 2, Page. 2324-2333 | en_US |
dc.identifier.issn | 2168-0485 | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acssuschemeng.7b03680 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/105369 | - |
dc.description.abstract | Highly N-doped nanoporous carbons have been of great interest as a high uptake CO2 adsorbent and as an efficient metal-free oxygen reduction reaction (ORR) catalyst. Therefore, it is essential to produce porosity-tunable and highly N-doped carbons through cost-effective means. Herein, we introduce the bioinspired synthesis of a monodisperse and N-enriched melaninlike polymer (MP) resembling the sepia biopolymer (SP) from oceanic cuttlefish. These polymers were subsequently utilized for highly N-doped synthetic carbon (MC) and biomass carbon (SC) spheres. An adequate CO2 activation process fine-tunes the ultramicroporosity (˂1 nm) of N-doped MC and SC spheres, those with maximum ultramicroporosities of which show remarkable CO2 adsorption capacities. In addition, N-doped MC and SC with ultrahigh surface areas of 2677 and 2506 m(2)/g, respectively, showed excellent ORR activities with a favored four electron reduction pathway, long-term durability, and better methanol tolerance, comparable to a commercial Pt-based catalyst. | en_US |
dc.description.sponsorship | This work was supported by the basic science research program of the National Research Foundation (2016R1D1A1B03930258) and the Institute of Basic Science (IBS-R006-G1) in Republic of Korea | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.subject | Bioinspired synthesis | en_US |
dc.subject | Biomass | en_US |
dc.subject | CO2 adsorption | en_US |
dc.subject | N-doped carbon | en_US |
dc.subject | Oxygen reduction reaction | en_US |
dc.title | Bioinspired Synthesis of Melaninlike Nanoparticles for Highly N-Doped Carbons Utilized as Enhanced CO2 Adsorbents and Efficient Oxygen Reduction Catalysts | en_US |
dc.type | Article | en_US |
dc.relation.no | 2 | - |
dc.relation.volume | 6 | - |
dc.identifier.doi | 10.1021/acssuschemeng.7b03680 | - |
dc.relation.page | 2324-2333 | - |
dc.relation.journal | ACS SUSTAINABLE CHEMISTRY & ENGINEERING | - |
dc.contributor.googleauthor | Kim, Hee Soo | - |
dc.contributor.googleauthor | Kim, Minhyoung | - |
dc.contributor.googleauthor | Kang, Min Seok | - |
dc.contributor.googleauthor | Ahn, Jihoon | - |
dc.contributor.googleauthor | Sung, Yung-Eun | - |
dc.contributor.googleauthor | Yoo, Won Cheol | - |
dc.relation.code | 2018011148 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E] | - |
dc.sector.department | DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING | - |
dc.identifier.pid | wcyoo | - |
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