Targeted Synthesis of a Prototype MOF Based on Zn4(O)(O2C)6 Units and a Nonlinear Dicarboxylate Ligand

Title
Targeted Synthesis of a Prototype MOF Based on Zn4(O)(O2C)6 Units and a Nonlinear Dicarboxylate Ligand
Author
전형필
Keywords
METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; ADSORPTION; SORPTION; NETS; MICROPOROSITY; CATENATION; TOPOLOGY; BINDING; MOTIFS
Issue Date
2008-12
Publisher
AMER CHEMICAL SOC
Citation
INORGANIC CHEMISTRY, v. 48, No. 2, Page. 417-419
Abstract
A surprisingly small number of topologies are known in metal-organic frameworks (MOFs) that possess Zn-4(O)(O2C)(6) building units. One of such MOFs having a simple, nonlinear dicarboxylate ligand, 5-methylisophthalate (mip), is targeted and successfully synthesized. The framework, [Zn-4(O)(mip)(3)], is based on a nonuniform, uninodal six-connected net and is featured by complicated meshlike pores with narrow passages. Gas sorption studies reveal the potentials as a prototype from which new MOFs having interesting properties can be derived.
URI
https://pubs.acs.org/doi/abs/10.1021/ic801906ehttp://repository.hanyang.ac.kr/handle/20.500.11754/105255
ISSN
0020-1669
DOI
10.1021/ic801906e
Appears in Collections:
COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > CHEMICAL AND MOLECULAR ENGINEERING(화학분자공학과) > Articles
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