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dc.contributor.author전형필-
dc.date.accessioned2019-05-17T02:24:35Z-
dc.date.available2019-05-17T02:24:35Z-
dc.date.issued2008-05-
dc.identifier.citationINORGANIC CHEMISTRY, v. 47, No. 12, Page. 5355-5359en_US
dc.identifier.issn0020-1669-
dc.identifier.urihttps://pubs.acs.org/doi/abs/10.1021/ic800274w-
dc.identifier.urihttps://repository.hanyang.ac.kr/handle/20.500.11754/104547-
dc.description.abstractTwo new metal-organic frameworks based on trinuclear pinwheel motifs are prepared using dicarboxylate and diamine ligands. The structure of (CO3(bdC)(3)(dabco)] (1) (bdc = 1,4-benzenedicarboxylate; dabco = 1,4-diazabicyclo[2.2.2]octane) is described as pillared layers, whereas [Co-3(ndc)(3)(dabco)] (2) (ndc = 2,6-naphthalenedicarboxylate) forms a variation of primitive cubic net with 3D connected pores. The two 8-connected MOFs are thermally stable at 160 and 250 degrees C for 1 and 2 respectively in the air and possess corrugated channels owing to the high connectivities of the secondary building unit. As a result, they show highly efficient hydrogen sorption capabilities. Especially, a high hydrogen uptake (2.45 wt % at 77 K and 1 bar) is observed for 2 that has the unique combination of high surface area and small portals.en_US
dc.language.isoen_USen_US
dc.publisherAMER CHEMICAL SOCen_US
dc.subjectMETAL-ORGANIC FRAMEWORKSen_US
dc.subjectCOORDINATION POLYMERSen_US
dc.subjectSTORAGEen_US
dc.subjectADSORPTIONen_US
dc.subjectBINDINGen_US
dc.titleEfficient Hydrogen Sorption in 8-Connected MOFs Based on Trinuclear Pinwheel Motifsen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/ic800274w-
dc.relation.journalINORGANIC CHEMISTRY-
dc.contributor.googleauthorChun, Hyungphil-
dc.contributor.googleauthorJung, Heejin-
dc.contributor.googleauthorKoo, Gumae-
dc.contributor.googleauthorJeong, Heondo-
dc.contributor.googleauthorKim, Dong-Kook-
dc.relation.code2008204045-
dc.sector.campusE-
dc.sector.daehakCOLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E]-
dc.sector.departmentDEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING-
dc.identifier.pidhchun-


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