Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 전형필 | - |
dc.date.accessioned | 2019-05-17T02:24:35Z | - |
dc.date.available | 2019-05-17T02:24:35Z | - |
dc.date.issued | 2008-05 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v. 47, No. 12, Page. 5355-5359 | en_US |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | https://pubs.acs.org/doi/abs/10.1021/ic800274w | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/104547 | - |
dc.description.abstract | Two new metal-organic frameworks based on trinuclear pinwheel motifs are prepared using dicarboxylate and diamine ligands. The structure of (CO3(bdC)(3)(dabco)] (1) (bdc = 1,4-benzenedicarboxylate; dabco = 1,4-diazabicyclo[2.2.2]octane) is described as pillared layers, whereas [Co-3(ndc)(3)(dabco)] (2) (ndc = 2,6-naphthalenedicarboxylate) forms a variation of primitive cubic net with 3D connected pores. The two 8-connected MOFs are thermally stable at 160 and 250 degrees C for 1 and 2 respectively in the air and possess corrugated channels owing to the high connectivities of the secondary building unit. As a result, they show highly efficient hydrogen sorption capabilities. Especially, a high hydrogen uptake (2.45 wt % at 77 K and 1 bar) is observed for 2 that has the unique combination of high surface area and small portals. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.subject | METAL-ORGANIC FRAMEWORKS | en_US |
dc.subject | COORDINATION POLYMERS | en_US |
dc.subject | STORAGE | en_US |
dc.subject | ADSORPTION | en_US |
dc.subject | BINDING | en_US |
dc.title | Efficient Hydrogen Sorption in 8-Connected MOFs Based on Trinuclear Pinwheel Motifs | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1021/ic800274w | - |
dc.relation.journal | INORGANIC CHEMISTRY | - |
dc.contributor.googleauthor | Chun, Hyungphil | - |
dc.contributor.googleauthor | Jung, Heejin | - |
dc.contributor.googleauthor | Koo, Gumae | - |
dc.contributor.googleauthor | Jeong, Heondo | - |
dc.contributor.googleauthor | Kim, Dong-Kook | - |
dc.relation.code | 2008204045 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E] | - |
dc.sector.department | DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING | - |
dc.identifier.pid | hchun | - |
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