Metal-Free One-Pot Synthesis of N,N '-Diarylamidines and N-Arylbenzimidazoles from Arenediazonium Salts, Nitriles, and Free Anilines
- Title
- Metal-Free One-Pot Synthesis of N,N '-Diarylamidines and N-Arylbenzimidazoles from Arenediazonium Salts, Nitriles, and Free Anilines
- Author
- 윤소원
- Keywords
- C-H AMINATION; DIAZONIUM SALTS; BENZIMIDAZOLE DERIVATIVES; IRIDIUM(III) COMPLEXES; PHENYL CATIONS; BOND FORMATION; LEAVING GROUP; AMIDINES; ARYLATION; CHEMISTRY
- Issue Date
- 2016-11
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v. 18, NO 21, Page. 5728-5731
- Abstract
- A highly efficient and facile metal-free, one-pot reaction has been developed to afford diversely substituted N-arylbenzimidazoles through chemoselective in situ generation of N,N'-diarylamidines from arenediazonium salts, nitrites, and free anilines. The advantages of this protocol consist of the operationally easy and simple one-pot procedure under metal-free and mild conditions, the direct use of inexpensive and commercially available chemicals, and thus, a cost-effective and greener process.
- URI
- https://pubs.acs.org/doi/10.1021/acs.orglett.6b02994https://repository.hanyang.ac.kr/handle/20.500.11754/101001
- ISSN
- 1523-7060; 1523-7052
- DOI
- 10.1021/acs.orglett.6b02994
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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